Product ID:CHLORO SOLV
MSDS Date:03/01/1988
FSC:7930
NIIN:00N010039
MSDS Number: BHTZC

STATE CHEMICAL MANUFACTURING CO.

3100 HAMILTON AVENUE
CLEVELAND, OH 44114

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III)

CAS: 123-91-1

RTECS: JG8225000

Fraction By Weight: <2%

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PERCHLOROETHYLENE (TETRACHLOROETHYLENE) (SARA III)

CAS: 127-18-4

RTECS: KX3850000

Fraction By Weight: <30%

OSHA PEL 100 PPM

ACGIH TLV: 25PPM/100,A3 STEL;94

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: <80%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

DO NOT USE IN GEN VICIN OF ARC WELDING,OPEN

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:WARNING:HARMFUL OR FATAL IF
SWALLOWED.OVEREXPOSURE TO THIS MATERIAL OR ITS COMPONENTS HAS BEEN
SUGGESTED AS A CAUSE OF LIVER ABNORMALITIES,KIDNEY DAMAGE,LUNG
DAMAGE,BRAIN DAMAGE,AND SPLEEN DAMAGE IN H UMANS.
Explanation of Carcinogenicity:PERCHLOROETHYLENE & DIETHYLENE
ETHER:INAD EVID FOR CARCIN IN HUMANS;SUFF EVID FOR CARC IN ANIMALS
(IARC,1987).(SEE SUPP)
Effects of Overexposure:EYES:IRRITATION.SKIN:ANESTHETIC
EFFECTS.INGESTION:HARMFUL OR FATAL IF SWALLOWED.INHALATION:VAPOR
HARMFUL.PROLONGED OVEREXPOSURE MAY RESULT IN
HEADACHE,DIZZINESS,DROWSINESS OR NAUSEA,NASAL & RESPIRATOR Y
IRRITATION.
Medical Cond Aggravated by Exposure:LIVER DISEASE AND RHYTHM DISORDERS
OF THE HEART.

First Aid:EYES:FLUSH IMMED W/ PLENTY OF COOL WATER FOR AT LEAST 15
MIN.IF IRRIT PERSISTS,GET MED ATTN.SKIN:WASH IMMED W/ PLENTY OF
SOAP & WATER.REMOVE SOAKED CLTHG.IF IRRIT PERSISTS,CALL
MD.INGEST:GET MED ATTN IMMED.IF NOT AVAILABLE,INDUCE VOMIT USING
SYRUP OF IPECAC (FOLLOW LABEL) OR BY PLACING FINGER AT BACK OF
THROAT.DO NOT MAKE UNCON PERSON VOMIT.INHAL:REMOVE TO FRESH AIR.GET
MED ATTN IMMED.(SEE SUPP)

Flash Point:NONE
Lower Limits:N/K
Upper Limits:N/K
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:N/A.THERMAL DECOMPOSITION (TEMPERATURES
ABOVE 500C,932F) MAY RESULT IN FORMATION OF HYDROCHLORIC
ACID,PHOSGENE,CHLORINE GAS OR CARBON MONOXIDE.

Spill Release Procedures:VENTILATE AREA.ABSORB SPILL ON OIL
ABSORBENT,SAND OR VERMICULITE.
Neutralizing Agent:N/K

Handling and Storage Precautions:KEEP CLSD WHEN NOT IN USE.DO NOT USE
ALUMINUM CONTRS.DO NOT REUSE EMPTY DRUM,RETURN TO
RECONDITIONER/DESTROY BY CRUSHING.MAY ATTACK PLASTICS,(SUP DA)
Other Precautions:READ/FOLLOW ALL LABEL DIRECTIONS/PREC.FOR INDUST USE
ONLY.NOT FOR HOUSEHOLD USE/RESALE.KEEP OUT OF REACH OF CHILDREN.DO
NOT DILUTE,HEAT,USE VAP IN VAP DEGREASING.USE EXTRA CAUTION IN
HIGH-PRESS SPRAYI NG.NO SMKNG IN AREA OF USE.(SEE ING 4)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:REQUIRED
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH STATION OR SOURCE OF CLEAN WATER
NEARBY IN CASE OF ACCIDENTAL EYE SPLASHING.NEOPRENE APRON IS
OPTIONAL.
Work Hygienic Practices:DO NOT WEAR CONTACT LENSES.
Supplemental Safety and Health
VOLAT BY WT:100%.FL PT METH:TCC,TOC,COC.EXPLAN OF CARCIN:SUSP HUMAN
CARC/KNOWN ANIMAL CARC (NTP,1985).FIRST AID PROC:IF BREATHING STOPS
GIVE ARTF RESP.MD NOTE-DO NOT GIVE STIMULANTS.EPINEPHRINE OR EPH
EDRINE AFFECT HEART W/ FATAL RESULTS.HNDLG/STOR PREC:TESTING
REC.AVOID SKIN,EYE,CLOTHING CONTACT.DO NOT INGEST.

Boiling Pt:B.P. Text:165-251F
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Spec Gravity:1.385 (WATER=1)
Evaporation Rate & Reference:N/K
Solubility in Water:NEGLIGIBLE
Appearance and Odor:A CLEAR BLUE LIQUID WITH A CHLORINATED ODOR.

Stability Indicator/Materials to Avoid:YES
PURE OXYGEN,STRONG CAUSTICS,STRONG OXIDIZERS AND CHEMICALLY ACTIVE
LIGHT METALS SUCH AS ALUMINUM,LITHIUM & SODIUM.
Stability Condition to Avoid:AVOID OPEN FLAMES,HOT GLOWING SURFACES OR
ELECTRIC ARCS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION (TEMPERATURES
ABOVE 500C,932F) MAY RESULT IN FORMATION OF HCL
ACID,PHOSGENE,CHLORINE GAS OR CO.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .OPEN DUMPING IS
PROHIBITED.USED CHLORO-SOLV IS A RCRA HAZ WASTE.PRODUCT CONTAINS
PERCHLOROETHYLENE (ETHYLENE TETRACHLORID E) WHICH HAS A REPORTABLE
QUANTITY OF 100 LBS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.